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3.5 Samarium-Cobalt Permanent Magnet

Samarium-cobalt permanent magnets are primarily composed of elements such as samarium (Sm), cobalt (Co), copper (Cu), iron (Fe), and zirconium (Zr). Structurally, they are classified into two types—the 1:5 type and the 2:17 type—and are categorized as first- and second-generation rare earth permanent magnet materials. Samarium-cobalt magnets possess exceptional magnetic properties (including high remanence, high coercivity, and a high maximum energy product), an extremely low temperature coefficient, a high maximum operating temperature, and strong corrosion resistance. Currently, they represent the optimal permanent magnet material for high-temperature applications and are widely utilized across industries involving microwave devices, electron beam equipment, high-power and high-speed motors, sensors, and magnetic components.

2:17 Type Samarium-Cobalt Magnets

2:17 type samarium-cobalt magnets, also known as Sm2Co17, feature maximum energy products ranging from 20 to 35 MGOe across various grades, with a maximum operating temperature of 500°C. Possessing a low temperature coefficient and excellent corrosion resistance, 2:17 type magnets outperform Neodymium-Iron-Boron (NdFeB) magnets in terms of magnetic performance at high temperatures. Consequently, they are widely utilized in aerospace, military applications, high-temperature motors, automotive sensors, various magnetic drive systems, magnetic pumps, and microwave devices. 2:17 type samarium-cobalt magnets are highly brittle, making it difficult to fabricate them into complex shapes, extremely thin sheets, or thin-walled rings. Furthermore, minor chipping or corner damage may occur during the manufacturing process; generally, provided that such imperfections do not compromise the magnetic properties or functional performance of the product, they are considered acceptable.

In terms of performance characteristics, samarium-cobalt permanent magnets can be broadly categorized into three series: the High-Performance Series, the High-Stability Series (featuring a low temperature coefficient), and the High-Temperature Resistance Series.

1:5 Type Samarium-Cobalt Magnets

1:5 type samarium-cobalt magnets are also referred to as Samarium-Cobalt 5 or SmCo5. Across various grades, their maximum energy product ranges from 16 to 25 MGOe, and they possess a maximum operating temperature of 250°C. While their maximum energy product is lower than that of the 2:17 type samarium-cobalt, their mechanical properties and ductility are slightly superior to the 2:17 type. Consequently, they are well-suited for being machined into shapes and specifications that are difficult to produce using the 2:17 type—such as discs, squares, rings, and various complex or irregular geometries featuring particularly thin cross-sections or walls.

The magnetizing field required for 1:5 type samarium-cobalt magnets is lower than that for the 2:17 type; typically, a magnetic field of 40,000 Gauss is sufficient to achieve magnetic saturation, whereas high-coercivity 2:17 type samarium-cobalt magnets require a magnetizing field of 60,000 Gauss or higher. Furthermore, the composition of 1:5 type samarium-cobalt magnets contains a rare earth content of nearly 40%, resulting in a higher unit price compared to 2:17 type samarium-cobalt magnets.

Other Properties of Samarium-Cobalt Permanent Magnets

The national standards for the auxiliary electromagnetic properties and selected mechanical and physical properties of sintered rare-earth cobalt permanent magnet materials are as follows:

Due to variations in the organic binders and molding methods employed for bonded rare-earth cobalt permanent magnets, their magnetic and material properties exhibit significant differences; consequently, the state has not established a unified standard for them.

Differences Between Samarium-Cobalt and Neodymium-Iron-Boron Magnets

  1.  **Composition Differences**

In Neodymium-Iron-Boron (NdFeB) permanent magnets, the rare-earth metal neodymium accounts for approximately 29% to 32.5%; the metallic element iron accounts for 64% to 69%; and the non-metallic element boron accounts for 1.1% to 1.2%. Additionally, small amounts of other elements—such as dysprosium, terbium, niobium, and copper—are added.

For Samarium-Cobalt (SmCo) magnets—taking the 2:17 type as an example—the rare-earth metal samarium accounts for 23% to 28%; the metallic element cobalt accounts for 48% to 52%; and the metallic element iron accounts for 14% to 17%. Furthermore, small amounts of other elements, such as copper and zirconium, are present.

  1.  **Differences in Performance and Price**

As indicated by the performance tables mentioned previously, the overall magnetic properties of Samarium-Cobalt permanent magnets are generally lower than those of Neodymium-Iron-Boron permanent magnets. An examination of the elemental ratios in both types reveals that NdFeB magnets possess the highest iron content, whereas SmCo magnets consist of approximately 70% samarium and cobalt. Consequently, when comparing two magnets—one SmCo and one NdFeB—of identical magnetic energy product and volume, the price of the SmCo magnet is typically slightly higher.

  1.  **Differences in High-Temperature Resistance, Oxidation Resistance, and Corrosion Resistance**

The operating temperature range for Neodymium-Iron-Boron permanent magnets is between 80°C and 220°C, whereas the operating temperature for Samarium-Cobalt permanent magnets can reach 250°C to 350°C.

Due to their high iron content, Neodymium-Iron-Boron magnets are susceptible to oxidation and corrosion; therefore, surface treatment is an essential process. The service life of these magnets depends largely on the effectiveness of the protective coating. In contrast, Samarium-Cobalt magnets contain a lower proportion of iron and are composed primarily of metallic elements that are inherently resistant to oxidation and corrosion. Under normal circumstances, surface treatment is not required for SmCo magnets; plating is typically applied only when the operating environment is particularly harsh or when an enhanced aesthetic appearance is desired